科研之友
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摘要
P,C-Stereogenic -amino phosphine oxides were prepared from the addition of (R-P)-menthyl phenyl phosphine oxide to chiral aldimines under neat condition at 80 degrees C in up to 91:9 dr(C) and 99% yields. The diastereoselectivity was mainly induced by chiral phosphorus that showed matched or mismatched induction with (S)- or (R)-aldimines, respectively. Chirality 28:132-135, 2016.
- 出版日期2016-2
- 单位聊城大学
