Alkylation of isobutane/1-butene over periodic mesoporous organosilica functionalized with perfluoroalkylsulfonic acid group

作者：Shen Wei; Dube David; Kaliaguine Serge^*

来源：Catalysis Communications, 2008, 10(3): 291-294.

DOI：10.1016/j.catcom.2008.09.016

A periodic mesoporous organosilica (PMO) has been sucessfully functionalized with perfluoroalkylsulfonic acid groups by reacting the PMO with 1,2,2-trifluoro-2-hydroxy-1-trifluoromethylethane sulfonic acid beta-sultone. The resulting material exhibits much higher catalytic activity in the alkylation of isobutane by 1-butene than perfluoroalkylsulfonic acid functionalized SBA-15, alkylsulfonic acid functionalized PMO and zeolite Y. PMO and zeolite Y.

• 出版日期2008-12-15
• 单位复旦大学