A new process developed for separation of lignin from ammonium hydroxide pretreatment solutions

作者:Sherman Steven R*; Goodell John J; Milliken Charles E; Morris Jacob A; Gorensek Maximilian B
来源:Environmental Progress & Sustainable Energy, 2012, 31(1): 130-138.
DOI:10.1002/ep.10544

摘要

A method is described for separating lignin from liquid solutions resulting from the pretreatment of lignocellulosic materials such as switchgrass with ammonium hydroxide. The method involves a sequence of steps including acidification, evaporation, and precipitation or centrifugation that are performed under defined conditions, and results in a relatively pure, solid lignin product. The method is tested on ammonium hydroxide solutions containing lignin extracted from switchgrass. Experimental results show that the method is capable of recovering between 6695% of dissolved lignin as a precipitated solid. Cost estimates of pilot-scale and industrial-scale expressions of the process indicate that breakeven lignin prices of $2.36/kg and $0.78/kg, respectively, may be obtainable with this recovery method.

  • 出版日期2012-4