Alkylzinc diorganophosphates: synthesis, structural diversity and unique ability to incorporate zincoxane units

作者：Wolska Pietkiewicz Malgorzata; Swierkosz Adam; Justyniak Iwona; Grala Agnieszka; Sokolowski Kamil; Lewinski Janusz^*

来源：Dalton Transactions, 2016, 45(47): 18813-18816.

DOI：10.1039/c6dt03324e

Equimolar reactions between ZntBu(2) and diphenyl phosphate (dpphe-H) or dimethyl phosphate (dmphe-H) result in the formation of [tBuZn(O2P(OR')(2))]-type compounds which crystallize as tetranuclear aggregates, [tBuZn(dpphe)](4) (1(4)) or [tBuZn(dmphe)](4) (2(4)), with the phosphate ligands spanning 4-coordinate Zn centers. The utility of ZnMe2 instead of ZntBu(2) dramatically changes the reaction outcome and leads to [MeZn(O2P(OR')(2))]-type moieties incorporating zincoxane units, i.e., pentanuclear [{MeZn(dpphe)}(3)(Me2Zn2O)(THF)(2)] (3) and nonanuclear [{MeZn(dmphe)}(6)(Me2Zn3O2)] (4) aggregates. The resulting compounds were characterized by H-1 and P-31 NMR spectroscopy and single-crystal X-ray diffraction analysis.

• 出版日期2016-12-21