New Routes for Preparation and Characterization of [Au-2(C N)(2)P(Ph)(2)CH2P(Ph)(2)] Complex

作者：Jaafar Mohammed H^*; Al Ohaly A A

来源：Asian Journal of Chemistry, 2013, 25(2): 642-644.

DOI：10.14233/ajchem.2013.11983

• [Au(CN)](n)
• Gold complexes
• Gold Cyanide
• Bis(diphenylphosphino)methane

The gold complex i.e., [Au-2(C N)(2)P(Ph)(2)CH2P(Ph)(2)] has been successfully produced by three reactions, the reaction of polymeric gold cyanide [Au(CN)](n) with a suspension of bis(diphenylphosphino)methane (dppm), in acetone in a 2:1, pure ammonia (NH3), [Au(C N)](n) and (Ph)(2)PCH2P(Ph)(2) in acetone in a 2:2:1 or that of [Au(C N)(NH3)(2)] with (Ph)(2)PCH2P(Ph)(2) in acetone in a 1:0.5 giving a white precipitate collected as Au-2(C N)(2)P(Ph)(2)CH2P(Ph)(2). The complex was characterized by elemental analysis, FT-IR and NMR spectroscopy and found in agreement with the proposed formula C27H22N2P2Au2.

• 出版日期2013-2