Diaquabis(4-bromo-2-formylphenolato-kappa O-2,O')cobalt(II)

作者：Xiao, Yu^*; Zhang, Min

来源：Acta Crystallographica Section E-Structure Reports Online, 2008, 64: M1231-U164.

DOI：10.1107/S1600536808026068

In the title complex, [Co(C7H4BrO2)(2)(H2O)(2)], the Co-II ion, which lies on a crystallographic inversion center, is coordinated by four O atoms from two bidentate 4-bromo-2-formylphenolate ligands and two O atoms from two water ligands in a slightly distorted octahedral environment. In the crystal structure, one-dimensional chains are formed through intermolecular O- H center dot center dot center dot O hydrogen bonds, which are further linked into a two-dimensional network through Br center dot center dot center dot Br interactions [Br center dot center dot center dot Br = 3.772 (4) (A) over circle].

• 出版日期2008-10
• 单位桂林理工大学