A new room temperature phase of diammonium hexafluorogermanate(IV), (NH4)(2)[GeF6]

作者:Gobel Ole F*; ten Elshof Johan E; Smits Jan
来源:Zeitschrift fur Kristallographie-Crystalline Materials, 2011, 226(6): 531-534.
DOI:10.1524/zkri.2011.1394

摘要

Single crystals of diammonium hexafluorogermanate(IV), (NH4)(2)[GeF6], grown at room temperature, have hexagonal symmetry with space group P6(3)mc. So far, only a trigonal room temperature phase and a cubic phase grown at 50 degrees C were known. We refined the crystal structure, excluding the hydrogen atoms, and measured refractive indices and birefringence.

  • 出版日期2011

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