Dechlorination/detoxification of aromatic chlorides using fly ash under mild conditions

作者:Ghaffar Abdul*; Tabata Masaaki
来源:Waste Management, 2009, 29(12): 3004-3008.
DOI:10.1016/j.wasman.2009.06.013

摘要

An efficient dechlorination/detroxification method for p-nitrochlorobenzene, p-chloroanisole and 1-chloronaphthalene on municipal waste incinerator fly ash in presence of reducing agents with water/alcohol mixtures was developed. Dechlorination% was higher in water/isopropanol mixture at temperature <100 degrees C. Metal contents of fly ash played a vital role in enhancing dechlorination at low temperature. Moreover, the fly ash particles provided the surface to accomplish reduction and substitution reactions by adsorbing the chlorinated aromatic compound, hydrogen and hydroxyl ions. The mechanism of dechlorination was envisaged.

  • 出版日期2009-12