Assembly of co-bimb-polyoxotungstate hybrids: from 1D chain to 3D framework influenced by the charge of Keggin anions

作者：Yu, Tingting^*; Wang, Kun; Ma, Huiyuan; Pang, Haijun; Li, Shaobin

来源：RSC Advances, 2014, 4(5): 2235-2241.

DOI：10.1039/c3ra45456h

• METAL-ORGANIC FRAMEWORK
• COORDINATION POLYMER
• POLYOXOMETALATE COMPLEX
• CRYSTAL-STRUCTURES
• BUILDING-BLOCKS
• CU-I
• LIGAND
• CLUSTERS
• UNITS
• IONS

Two new inorganic-organic hybrid compounds: [Co(H2O)(2)(bimb)(2)](2)[SiW12O40] (1) and [Co-2(H2O)(bimb)(4)](HBW12O40)center dot H2O (2) (bimb 1,3-bis(1-imidazoly) benzene), have been synthesized under the same hydrothermal conditions and characterized by single crystal X-ray diffraction, IR spectra, elemental analyses and powder X-ray diffraction. Structural analyses show that 1 displays a 1D polymeric chain, whereas 2 presents a complicated 3D self-penetrating framework. The distinct structural features of the two compounds suggest that the charge of the Keggin anions should play a significant role in the process of assembly. The electrochemical properties of 1 and 2 were investigated in detail.

• 出版日期2014
• 单位黑龙江大学; 哈尔滨学院