An Easy Route to (Hetero) arylboronic Acids

作者:Erb William; Hellal Akila; Albini Mathieu; Rouden Jacques; Blanchet Jerome*
来源:Chemistry - A European Journal, 2014, 20(22): 6608-6612.
DOI:10.1002/chem.201402487

摘要

An unprecedented spontaneous reactivity between diazonium salts and diboronic acid has been unveiled, leading to a versatile arylboronic acid synthesis directly from (hetero)arylamines. This fast reaction (35min overall) tolerates a wide range of functional groups and is carried out under very mild conditions. The radical nature of the reaction mechanism has been investigated.

  • 出版日期2014-5-26