科研之友
微信
新浪微博
Facebook
分享链接
摘要
Chlorine dioxide based chemical oscillating behavior was modeled by a simple scheme consisting of three component reactions. Furthermore, little is known about the influence of the pH value. In this study, four component reactions were used to model the chlorite - iodide - ethyl acetoacetate oscillating reaction by dynamic analysis software. The oscillatory phenomenon is observed for concentration changes of triiodide ion, chlorite ion, and hydrogen ion. The initial concentration of ethyl acetoacetate, chlorite ion, iodide ion, and hydrogen ion has great influence on oscillations. The amplitude and number of oscillations are associated with the initial reactant concentrations. The equation of the reaction rate of triiodide ion, chlorite ion, or hydrogen ion changing with reaction time and initial concentrations in the oscillation stage was obtained. The bifurcation surface between oscillatory and nonoscillatory behavior with different pH values was obtained. The spatial zone for the occurrence of oscillation is reduced with an increase in the pH value. The range of oscillation as concentrations of chlorine dioxide, iodine, and ethyl acetoacetate is well described by an equation. There is a lower limit on ethyl acetoacetate initial concentration for oscillation. However, there is a higher limit on chlorine dioxide and iodine concentration for oscillation. The concentrations of chlorine dioxide and iodine for oscillation decrease with an increase in the pH value. The results provide new theoretical evidence of the importance of pH value, which can affect the bifurcation surface between oscillatory and nonoscillatory behavior.
- 出版日期2014-5
- 单位山东大学
