Decomposition of molybdate-hexamethylenetetramine complex: One single source route for different catalytic materials

作者：Chouzier Sandra; Czeri Tivadar; Roy Auberger Magalie; Pichon Christophe; Geantet Christophe; Vrinat Michel; Afanasiev Pavel^*

来源：Journal of Solid State Chemistry, 2011, 184(10): 2668-2677.

DOI：10.1016/j.jssc.2011.08.005

• Molybdenum
• Nitride
• Sulfide
• Catalyst
• Hexamethylenetetramine

Decomposition of ammonium heptamolybdate-hexamethylentetramine (HMTA) complex (HMTA)(2)(NH(4))(4)Mo(7)O(24)center dot 2H(2)O was studied as a function of treatment conditions in the range 300-1173 K. The evolution of solid products during decomposition was studied by thermal analysis and in situ EXAFS. Depending on the nature of the gas used for treatment, single phases of highly dispersed nitrides Mo(2)N, carbide Mo(2)C, or oxide MoO(2) can be obtained. The nature of the products obtained was explained by qualitative thermodynamical considerations. Morphology of the solids considerably depends on such preparation parameters as temperature and mass velocity of the gas flow. For the nitride-based materials, catalytic activity was evaluated in the model thiophene HDS reaction. It was demonstrated that NH(3)-treated samples showed better catalytic activity than N(2)-treated ones due to cleaner surface and better morphology. Transmission microscopy, XRD and XPS studies showed that MoS(2) is formed on the surface during HDS reaction or sulfidation with H(2)S. Optimized nitride-derived catalysts showed mass activity several times higher than unsupported MoS(2) or MoS(2)/Al(2)O(3) reference catalyst.

• 出版日期2011-10