A novel Cd(II) complex with 1,3-bis(4-Pyridyl)propane: Synthesis, crystal structure, and interaction with DNA

作者：Gao, E. J.^*; Xu, X. Y.; Zhu, M. C.; Yan, H. L.; Fu, H.; Wang, H.; Zhan, L.; Yao, Q.; Li, M. Y.; Jiang, M. P.

来源：Russian Journal of Coordination Chemistry, 2014, 40(8): 583-587.

DOI：10.1134/S107032841408003X

• PLATINUM(II) COMPLEXES
• SPECTRAL PROPERTIES
• HYDROGEN-BOND
• BINDING
• PALLADIUM(II)
• LIGANDS
• NUCLEI

The complex [Cd(Bpp)(3)Cl-2] (n) center dot 2H(2)O (Bpp = 1,3-bis(4-pyridyl)propane) has been synthesized and characterized by elementary analysis, IR spectrum and singel-crystal X-ray diffraction. The crystal belongs to monoclinic system, space group C2/c with the crystal cell parameters of a = 31.05(3), b = 17.556(13), c = 16.281(13) beta = 121.402(7)A degrees, V = 7574(10) (3), and Z = 8. The compound has formed a 1D surface shape structure through these coordinate modes with the ligand. The 2D layers are further aggregated by hydrogen bonding with octameric subunits.

• 出版日期2014-8
• 单位沈阳化工大学