Nitrogen-enriched porous carbon supported Pd-nanoparticles as an efficient catalyst for the transfer hydrogenation of alkenes

作者：Li, Jie; Zhou, Xin; Shang, Ning-Zhao^*; Feng, Cheng; Gao, Shu-Tao; Wang, Chun^*

来源：New Journal of Chemistry, 2018, 42(20): 16823-16828.

DOI：10.1039/c8nj03656j

• OXYGEN REDUCTION REACTION
• C-H ACTIVATION
• N-DOPED CARBON
• PALLADIUM NANOPARTICLES
• FORMIC-ACID
• SELECTIVE HYDROGENATION
• C=C BOND
• OXIDATION
• VO-AT-G-C3N4
• NITROARENES

Ultrafine palladium nanoparticles were immobilized on nitrogen-enriched porous carbon nanosheets (NPC), which were fabricated with g-C3N4 as a nitrogen source and a self-sacrificial template. The prepared Pd@NPC exhibited superior catalytic activity and chemoselectivity for the catalytic transfer hydrogenation of alkenes under mild conditions with formic acid as a hydrogen donor. Moreover, the catalyst displays high structure stability, and can be reused for five runs without any significant decrease of its catalytic activity and obvious leaching of Pd species. This work provides a facile and feasible approach to fabricate nitrogen-enriched carbon nanosheets and to construct advanced Pd supported heterogeneous catalysts for achieving high catalytic activity.

• 出版日期2018-10-21
• 单位河北农业大学