Measurement of Critical Properties for Binary and Ternary Mixtures Containing n-Butanol and n-Alkane

作者：Wang, Chengjie; Chen, Junshuai; Salman, Muhammad; Liu, Xiangyang; Zhang, Ying; He, Maogang^*

来源：Journal of Chemical and Engineering Data, 2018, 63(10): 3956-3965.

DOI：10.1021/acs.jced.8b00585

• LIQUID CRITICAL PROPERTIES
• SUPERCRITICAL-FLUID EXTRACTION
• CRITICAL-TEMPERATURES
• THERMODYNAMIC PROPERTIES
• CRITICAL CONSTANTS
• CRITICAL PRESSURES
• VAPOR-PRESSURES
• HEAT-CAPACITY
• IONIC LIQUID
• PHASE-BEHAVIOR

The critical temperatures (T-c) and critical pressures (p(c)) of five binary mixtures of n-butanol + n-alkane (C = 6, 7, 8, 9, 10) as well as two ternary mixtures (n-butanol + hexane + heptane and n-butanol + heptane + octane) were measured over the whole concentration range using a flow method apparatus. The T-c of binary mixtures which contain heptane, octane, and nonane display a significant nonideality. The p(c) of binary mixtures increase with the increasing mole fraction of n-butanol and p(c)-x(1) curves rise up more obviously in richer n-butanol regions. The trends of the T-c-w(1) curves of two ternary mixtures slightly change with the increasing mass fraction of corresponding n-alkane components in mixtures. By using the Redlich-Kister equations, average absolute deviations (AADs) of binary mixtures were less than 0.09% and 0.

• 出版日期2018-10
• 单位西安交通大学