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摘要
A novel 3-D cuprous chloride polymer [Cu-2(I) Cl( mu 5-L)]n (1, HL = 1-tetrazole-4-imidazole-benzene) has been hydrothermally synthesized and structurally characterized. 1 displays a 3-D network with a bimodal fsc-3,5-Cmce-2 topological type constructed by the linkages of rare [(Cu2Cl)-Cl-I](+) cations and L- ligands. The photoluminescence properties and density functional theory calculations of 1 have also been studied.
- 出版日期2017-2-7
- 单位重庆师范大学
