[Zn-n(polyox)(pmtz)(n)]: the first polyoxalate-containing coordination polymer from an unforeseen chemical rearrangement of 5-pyrimidyltetrazole under hydrothermal conditions

作者：Rodriguez Dieguez A; Colacio E^*

来源：Chemical Communications, 2006, (39): 4140-4142.

DOI：10.1039/b608403f

The compound [Zn-2(polyox)(pmtz)(2)], which has been prepared by the hydrothermal reaction of ZnCl2 and Napmtz (5-pyrimidyl- tetrazolate), exhibits a unique 2D network with (6,3) topology, in which Zn-II ions are connected by pmtz- and polyoxalate-bridging ligands ( generated in situ from the breaking of the pmzt(-) ligand). This is the first structural report on a polyoxalate species.

• 出版日期2006