科研之友
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摘要
We show that ultrasound-induced mechanical force isomerizes an azobenzene centered within a poly(methyl acrylate) polymer from cis to trans configuration without cleaving the azo bond. The isomerization rate was not altered by the polarity of the solvent indicating that the isomerization occurs through a non-polar, inversion transition state.
- 出版日期2013
