Ni-2[LnCl(6)] (Ln = Eu-II, Ce-II, Gd-II): the first Ln(II) compounds stabilized in a pure inorganic lattice

作者：Baldo Bianca; Rubio Francisco; Flores Erwin; Vega Andres; Audebrand Nathalie; Venegas Yazigi Diego; Paredes Garcia Veronica^*

来源：Chemical Communications, 2018, 54(54): 7531-7534.

DOI：10.1039/c7cc09921e

Here we report the first examples of 3d-4f compounds based on Ln(II) cations. We have obtained a series of Ni-2[LnCl(6)] isostructural compounds where Ln(II) = Ce 1, Eu 2 and Gd 3 which were characterized in a cubic crystalline system with a Fm3m space group. Magnetic and optical characterization was also performed on this new class of compounds.

• 出版日期2018-7-11