科研之友
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摘要
Nonequilibrium mode-coupling theory (MCT) for uniformly sheared underdamped systems is developed, starting from the microscopic thermostated Sllod equation and the corresponding Liouville equation. Special attention is paid to the translational invariance in the sheared frame, which requires an appropriate definition of the transient time correlators. The derived MCT equation satisfies the alignment of the wave vectors and is manifestly translationally invariant. Isothermal condition is implemented by the introduction of current fluctuation in the dissipative coupling to the thermostat. This current fluctuation grows in the alpha relaxation regime, which generates a pronounced relaxation of the yield stress compared to the overdamped case. This result fills the gap between the molecular dynamics simulation and the overdamped MCT reported previously. The response to a perturbation of the shear rate demonstrates an inertia effect which is not observed in the overdamped case. Our theory turns out to be a nontrivial extension of the theory by Fuchs and Cates [J. Rheol. 53, 957 (2009)] to underdamped systems. Since our starting point is identical to that of Chong and Kim [Phys. Rev. E 79, 021203 (2009)], the contradictions between Fuchs-Cates and Chong-Kim are resolved. DOI: 10.1103/PhysRevE.87.012304
- 出版日期2013-1-4
