Design of main-chain polymers of chiral imidazolidinone for asymmetric organocatalysis application

作者:Haraguchi Naoki*; Kiyono Hitomi; Takemura Yu; Itsuno Shinichi
来源:Chemical communications, 2012, 48(33): 4011-4013.
DOI:10.1039/c2cc18115k

摘要

Main-chain polymers of chiral imidazolidinone were successfully synthesized by reaction of chiral imidazolidinone dimers with disulfonic acid. Chiral imidazolidinones were incorporated into the main-chain of the polymer by ionic bonding. These polymers could be used as polymeric chiral organocatalysts for asymmetric Diels-Alder reactions.

  • 出版日期2012