An unusual highly emissive water-soluble iridium lissamine-alanine complex and its use in a molecular logic gate

作者:Oliveira Elisabete*; Santos Sergio M; Nunez Cristina; Capelo Jose Luis; Lodeiro Carlos
来源:Dalton Transactions, 2016, 45(3): 1254-1258.
DOI:10.1039/c5dt03666f

摘要

The interaction of iridium(III) with a new lissamine rhodamine B sulfonyl derivative, bearing alanine as a building block, (1) with an orange emission in water results in a green highly emissive Ir@1 complex at room temperature. The new Ir@1 complex can sense the toxic Hg2+ metal ion and cysteine. Based on such properties, a new sophisticated molecular logic gate with three inputs was designed.

  • 出版日期2016