Mechanosynthesis of molybdenum carbides by ball milling at room temperature

作者：Xia Z P; Shen Y Q; Shen J J; Li Z Q^*

来源：Journal of Alloys and Compounds, 2008, 453(1-2): 185-190.

DOI：10.1016/j.jallcom.2006.11.166

• mechanical milling
• carbides
• metastable phase
• mechanically induced self-propagating reaction (MSR)

beta-Mo2C and high temperature phase eta-Mo3C2 were mechanosynthesised by ball milling mixtures (MoO3+2Al+xC) with different molar graphite contents (x = 0.5, 1.0, 1.25, 1.5, 1.75, 2.0) at room temperature. The experimental results and thermodynamic calculations reveal that the mechanosynthesis reactions were mechanically induced self-propagating reaction (MSR). The effects of graphite content on the phase constitution of the resultants were discussed. The structure and thermal stability of the molybdenum carbides were also studied.

• 出版日期2008-4-3
• 单位浙江大学