Active carbon/graphene hydrogel nanocomposites as a symmetric device for supercapacitors

作者：Ates Murat^*; Cinar Damla; Caliskan Sinan; Gecgel Unal; Uner Osman; Bayrak Yuksel; Candan Idris

来源：Fullerenes, Nanotubes, and Carbon Nanostructures, 2016, 24(7): 427-434.

DOI：10.1080/1536383X.2016.1174115

• thermal exfoliation
• Symmetric supercapacitor
• Energy density
• Graphene hydrogel
• Active carbon
• Power density

Activated carbons (ACs) are successfully synthesized from Elaeagnus grain by a simple chemical synthesis methodology and demonstrated as novel, suitable supercapacitor electrode materials for graphene hydrogel (GH)/AC nanocomposites. GH/AC nanocomposites are synthesized via hydrothermal process at temperature of 180 degrees C. The low-temperature thermal exfoliation approach is convenient for mass production of graphene hydrogel (GH) at low cost and it can be used as electrode material for energy storage applications. The GH/AC nanocomposites exhibit better electrochemical performances than the pure GH. Electrochemical performance of the electrodes is studied by cyclic voltammetry, and galvanostatic charge-discharge measurements in 1.0 M H2SO4 solution. A remarkable specific capacitance of 602.36 Fg(1) (based on GH/AC nanocomposites for 0.4 g AC) is obtained at a scan rate of 1 mVs(1) in 1 M H2SO4 solution and 155.78 Fg(1) for GH. The specific capacitance was increased 3.87 times for GH/AC compared to GH electrodes. Moreover, the GH/AC nanocomposites for 0.2 g AC present excellent long cycle life with 99.8% specific capacitance retained after 1000 charge/discharge processes. Herein, ACs prepared from Elaeagnus grain are synthesized GH and AC supercapacitor device for high-performance electrical energy storage devices as a promising substitute to conventional electrode materials for EDLCs.

• 出版日期2016