Microstructure of Polyisoprenes Synthesized with Titanium- and Neodymium-Containing Catalytic Systems

作者：Makhiyanov N^*; Akhmetov I G; Vagizov A M

来源：Polymer Science - Series A, 2012, 54(12): 942-949.

DOI：10.1134/S0965545X12090064

Polyisoprenes predominantly composed of cis-1,4- units are studied by the methods of NMR spectroscopy (600 MHz), GPC, and DSC. A comparative investigation of synthetic polyisoprene and natural rubbers shows that a small (up to 3-4 mol %) amount of polymer-chain disruptions, such as inverse additions of cis-1,4 units and units occurring in 3,4- and trans-1,4-configurations, has no effect on the local conformational structure of the polymer. DOI: 10.1134/S0965545X12090064

• 出版日期2012-12