Alkaline polymer electrolyte membranes from quaternized poly(phthalazinone ether ketone) for direct methanol fuel cell

作者：Zhang Hongwei^*; Zhou Zhentao

来源：Journal of Applied Polymer Science, 2008, 110(3): 1756-1762.

DOI：10.1002/app.28166

• quaternization
• poly(phthalazinone)
• alkaline polymer electrolyte membrane
• DMFC

Quaternized poly(phthalazinone ether ketone)s (QPPEK)s were synthesized by the chloromethylation and quaternization of poly(phthalazinone ether ketone) (PPEK) with chloromethyl methyl ether in 98% concentrated sulfuric acid and following trimethylamine. The presence of -CH2Cl groups in chloromethylated PPEK was confirmed by H-1-NMR. An alkaline QPPEK membrane was prepared and its thermal and mechanical properties were tested. The alkaline QPPEK membrane had a methanol permeability 6.57 X 10(-7) cm(2)/S and the highest anion conductivity 1.14 X 10(-2) S/cm.

• 出版日期2008-11-5
• 单位华南理工大学