Highly porous and robust scandium-based metal-organic frameworks for hydrogen storage

作者：Ibarra Ilich A; Yang Sihai; Lin Xiang; Blake Alexander J; Rizkallah Pierre J; Nowell Harriott; Allan David R; Champness Neil R^*; Hubberstey Peter; Schroeder Martin

来源：Chemical communications, 2011, 47(29): 8304-8306.

DOI：10.1039/c1cc11168j

The metal-organic frameworks NOTT-400 and NOTT-401, based on a binuclear [Sc(2)(mu(2)-OH)(O(2)CR)(4)] building block, have been synthesised and characterised; the desolvated framework NOTT-401a shows a BET surface area of 1514 m(2) g(-1) with a total H(2) uptake of 4.44 wt% at 77 K and 20 bar.

• 出版日期2011