First proton triggered C-ON bond homolysis in alkoxyamines

作者：Bremond Paul; Marque Sylvain R A^*

来源：Chemical communications, 2011, 47(14): 4291-4293.

DOI：10.1039/c0cc05637e

Rate constants k(d) of the C-ON bond homolysis in a new type of alkoxyamines (initiator/controller for Nitroxide Mediated Polymerization) carrying alkyl fragments capable of protonation were measured. A 20-fold increase was reported for the protonated alkoxyamine compared to the non-protonated homologue as predicted (Chem. Soc. Rev., 2011).

• 出版日期2011