A family of 'windmill'-like {Cu(6)Ln(12)} complexes exhibiting single-molecule magnetism behavior and large magnetic entropy changes

作者：Alexandropoulos Dimitris I; Poole Katye M; Cunha Silva Luis; Sheikh Javeed Ahmad; Wernsdorfer Wolfgang; Christou George; Stamatatos Theocharis C^*

来源：Chemical communications, 2017, 53(30): 4266-4269.

DOI：10.1039/c7cc01382e

A family of nanosized {Cu(6)Ln(12)} clusterswith a 'windmill'-like topology was prepared from the employment of 2,6-diacetylpyridine dioxime, in conjunction with bridging N-3(-), in 3d/4f-metal chemistry; the octadecanuclear compounds exhibit single-molecule magnetism behavior and large magnetic entropy changes, depending on the 4f-metal ion present.

• 出版日期2017-4-18