9-(2-Pyridylmethoxy)-1,10-phenanthrolin-1-ium perchlorate methanol solvate

作者：Zhang Shi Guo^*; Hou Chao

来源：Acta Crystallographica Section E-Structure Reports Online, 2008, 64: O1450-U1906.

DOI：10.1107/S1600536808020606

In the title organic salt, C18H14N3O+ center dot ClO4- center dot CH4O, there is a pi-pi stacking interaction between neighbouring 1,10-phenan-throline rings and the relevant distances are 3.5453 (18) angstrom for the centroid-centroid distance and 3.354 A for the perpendicular distance. There is also a relatively close contact between a C-H bond and a symmetry-related pyridine ring. There are classical N-H center dot center dot center dot O and O-H center dot center dot center dot N hydrogen bonds and non-classical C-H center dot center dot center dot O hydrogen bonds involving the cation, methanol solvent molecule and perchlorate anion.

• 出版日期2008-8
• 单位山东师范大学; 滨州学院