An ionic 2D inorganic-organic hybrid of tris[((1H-tetrazol-5-yl)methyl) morpholine] dodecatungstophosphate(V) pentahydrate: Synthesis X-ray crystal structure and spectroscopic characterizations

作者：Nikpour, Mohsen^*; Eshtiagh-Hosseini, Hossein; Mirzaei, Masoud; Kaju, Amir Aghaei; Chen, Ya Guang; Zarinabadi, Soroush

来源：Chinese Chemical Letters, 2010, 21(4): 501-505.

DOI：10.1016/j.cclet.2009.11.024

• Polyoxometalate
• Inorganic-organic hybrid
• Morpholine
• Dodecatungstophosphate
• Crystal structure

A unique ionic hybrid material [C(6)H(12)N(5)O](3)[(PO(4))W(12)O(36)]center dot 5H(2)O has been synthesized from the reaction of ((1H-tetrazole-5-yl)methyl)morpholine and alpha-H(3)[(PO(4)/W(12)O(36)]center dot 21H(2)O. It has successfully been characterized by elemental analysis, IR and (1)H NMR spectroscopies, TGA and single-crystal X-ray diffraction method. The title compound is constructed from the three [C(6)H(12)N(5)O](+) cations and alpha-Keggin [(PO(4))W(12)O(36)](3-) polyoxoanion. The most remarkable structural feature of this hybrid can be described as two-dimensional inorganic infinite plane-like (2D/infinity[PO(4))W(12)O(36)](3-)) which forming via van der Waals interactions along the x axis.

• 出版日期2010-4
• 单位东北师范大学