Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoire

作者：Cadenbach Thomas; Hevia Eva; Kennedy Alan R; Mulvey Robert E^*; Pickrell Janie Anne; Robertson Stuart D

来源：Dalton Transactions, 2012, 41(34): 10141-10144.

DOI：10.1039/c2dt31061a

New coordination complexes of the neutral tripodal tetraamine Me6TREN with tBu(3)Ga or tBu(2)Zn have been synthesised and studied with their molecular structures revealing, for the first time, coordination to metal centres via an eta(1) or eta(2) mode, adding to previously reported eta(3) and eta(4) ligated examples.

• 出版日期2012