Cooling and collisions of large gas phase molecules

作者:Patterson David*; Tsikata Edem; Doyle John M
来源:Physical Chemistry Chemical Physics, 2010, 12(33): 9736-9741.
DOI:10.1039/c002764b

摘要

Cold and dense samples of naphthalene (C(10)H(8)) are produced using buffer gas cooling in combination with rapid, high flow molecule injection. The observed naphthalene density is n approximate to 10(11) cm(-3) over a volume of a few cm(3) at a temperature of 6 K. We observe naphthalene-naphthalene collisions through two-body loss of naphthalene with a loss cross section of sigma(N-N) = 1.4 x 10(-14) cm(2). Analysis is presented that indicates that this combination of techniques will be applicable to many comparably sized molecules. This technique can also be combined with cryogenic beam methods(1) to produce cold, high flux, continuous molecular beams.

  • 出版日期2010