A [Mn18Dy] SMM resulting from the targeted replacement of the central Mn-II in the S=83/2 [Mn-19]-aggregate with Dy-III

作者：Ako Ayuk M; Mereacre Valeriu; Clerac Rodolphe; Wernsdorfer Wolfgang; Hewitt Ian J; Anson Christopher E; Powell Annie K^*

来源：Chemical communications, 2009, (5): 544-546.

DOI：10.1039/b814614d

Anisotropy can be introduced into the [Mn-19]-aggregate, which currently has the highest known spin ground state of S = 83/2, by the targeted replacement of the central Mn-II cation with Dy-III leading to a [Mn18Dy] complex with the same core topology showing slow relaxation of the magnetisation.

• 出版日期2009