A Facile Synthesis of β-Iodonitro Alkenes via Iodonitration of Alkynes with tert-Butyl Nitrite and Iodine

作者：Fan, Yuanyuan; Zhou, Bei; Chen, Kun; Wang, Bingtao; Li, Xiaoqing^*; Xu, Xiangsheng^*

来源：Synlett, 2017, 28(13): 1657-1659.

DOI：10.1055/s-0036-1588794

• beta-iodonitro alkenes
• iodonitration
• alkynes
• free radical
• difunctionalization

A convenient synthetic approach to beta-iodonitro alkenes based on the iodonitration of alkynes with (BuONO)-Bu-t and I-2 is described. No acid or oxidant is required in this reaction.

• 出版日期2017-8
• 单位浙江大学; 浙江工业大学; 浙江大学宁波理工学院