A facile photosynthesis of trans-dioxoruthenium(VI) porphyrins

作者:Huang Yan; Vanover Eric; Zhang Rui*
来源:Chemical Communications, 2010, 46(21): 3776-3778.
DOI:10.1039/c003094e

摘要

Photolysis of porphyrin-ruthenium(IV) dichlorate complexes with visible light results in homolytic cleavage of the O-Cl bond in the chlorates to form trans-dioxoruthenium(VI) species bearing either sterically encumbered or unencumbered porphyrin ligands.

  • 出版日期2010

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