Decacarbonyl-1 kappa C-3,2 kappa C-3,3 kappa C-4-mu-hydrido-1 : 2 kappa H-2 : H-(mu-quinoline-2-thiolato-1 : 2 kappa S-2 : S)diosmium(I)-osmium(0)(3 Os-Os)

作者：Sun Yu^*; Li Xiu Bing; Sun Bai Wang

来源：Acta Crystallographica Section E-Structure Reports Online, 2008, 64: M608-U64.

DOI：10.1107/S1600536808004881

The title compound, [Os-3(C9H6NS)H(CO)(10)], contains a nearly equilateral triangle of Os atoms. Two of the Os atoms are bridged by an S atom of the quinoline-2-thiolate ligand. Ten carbonyl groups complete the cluster, resulting in a distorted octahedral geometry for each Os atom. The hydride atom, which was located in a difference Fourier map and refined isotropically, bridges the shortest Os-Os edge.

• 出版日期2008-5
• 单位东南大学; 云南大学