A Three-Component 1D/2D → 2D Interpenetrated Coordination Network: Structure and Gas Adsorption Studies

作者:Chen, Jin-Xiang*; Ding, Ni-Ni; Chen, Ming; Chen, Wen-Hua; Young, David J.; Zhang, Wen-Hua; Hor, T. S. Andy
来源:Australian Journal of Chemistry, 2014, 67(10): 1391-1395.
DOI:10.1071/CH14111

摘要

We herein report a Cd-based coordination polymer containing three integrated polymeric components: two neutral and entangled two-dimensional (6,3) nets and one zwitterionic one-dimensional polymer with corner-sharing double-stranded chains propagating along the c-direction to lock the consecutive ligand struts of the (6,3) nets. Despite a sophisticated entanglement, this coordination polymer is porous to selectively adsorb CO2.