A novel 3D self-penetrating metal-organic framework with unprecedented 7-connectivity and entangled pattern

作者：Xu, Chunying; Ji, Bao-Ming^*; Miao, Shao-Bin; Deng, Dong-Sheng; Hou, Hongwei^*; Li, Minghui

来源：Polyhedron, 2017, 130: 160-164.

DOI：10.1016/j.poly.2017.04.001

• Self-penetrating network
• 7-Connectivity
• Nonequivalent shortest rings
• Entangled pattern
• Cadmium complex

A novel (4,4,7)-connected 3D self-penetrating network with unprecedented 7-connectivity, has been constructed using 1,4-bis(2-methylbenzimidazol-1-ylmethyl) benzene and 3,3',4,4'-Benzophenonetetracarboxylic acid as co-ligands. It represents an unusual self-penetrating pattern with the entanglements of nonequivalent 4- and 6-membered shortest rings.

• 单位
  洛阳师范学院; 郑州大学