Mechanochemically driven solid-state Diels-Alder reaction of graphite into graphene nanoplatelets

作者:Seo Jeong Min; Jeon In Yup; Baek Jong Beom*
来源:Chemical Science, 2013, 4(11): 4273-4277.
DOI:10.1039/c3sc51546j

摘要

A mechanochemically driven solid-state Diels-Alder reaction is demonstrated via dry ball-milling graphite as the diene in the presence of maleic anhydride or maleimide as the dienophile. On the basis of various characterizations, the Diels-Alder adducts are edge-selectively functionalized and subsequently delaminated into graphene nanoplatelets.

  • 出版日期2013