A high nuclear lanthanide-containing polyoxometalate aggregate synthesized in choline chloride/urea eutectic mixture

作者：Liu, Lin; Wang, Shi-Ming; Chen, Wei-Lin^*; Lu, Ying; Li, Yang-Guang; Wang, En-Bo

来源：Inorganic Chemistry Communications, 2012, 23: 14-16.

DOI：10.1016/j.inoche.2012.05.025

• Polyoxometalate
• Ionic liquid
• Eutectic mixture
• Lanthanide

A high nuclear lanthanide-containing polyoxometalate aggregate {[(CH3)(3)N(CH2)(2)OH](2)(NH4)(12)}[Ce-4(Mo-4) (H2O)(16)(Mo7O24)(4)]center dot 8H(2)O has been successfully synthesized in choline chloride/urea eutectic mixture. This method in synthesizing this anti-HIV activity aggregate has the advantages of convenience, facility, saving time and absence of additional noxious organic reagents. It has been characterized by XPS, IR, UV-vis spectra, TG analyses, power X-ray diffraction and single crystal X-ray diffraction. The CV property of the compound has also been tested.

• 出版日期2012-9
• 单位东北师范大学