A novel synthesis of calix[4]thiophenes and calix[4]furans

作者:Lee Gon Ann*; Wang Wen Chieh; Shieh Minghuey; Kuo Ting Shen
来源:Chemical Communications, 2010, 46(27): 5009-5011.
DOI:10.1039/c0cc00437e

摘要

The addition of heteroaryllithium to various ketones followed by dehydration gave 1-(2-heteroaryl)cycloalkenes and (2-heteroaryl)alkenes. When alkenes were treated with 10 mol% NIS, calix[4]thiophenes and calix[4]furans were obtained in good yields.

  • 出版日期2010