Analysis of ZFS parameters and local structure in Cr3+ ion doped into A(2)CdF(4) (A = Cs, K) fluorine compounds

作者：Acikgoz Muhammed^*

来源：Chemical Physics, 2016, 467: 38-43.

DOI：10.1016/j.chemphys.2015.12.007

• Electron magnetic resonance (EMR)
• Superposition model (SPM)
• Crystal structure
• Fluorine crystals
• Cr3+

An investigation of the zero-field splitting (ZFS) of Cr3+ ions at the centers with the tetragonal (TE) and orthorhombic (OR) symmetries has been carried out in Cr3+ ion doped into A(2)CdF(4) (A = Cs, K) fluorine compounds in the frame of semi-empirical superposition model (SPM). Various structural formations, namely uncompensated Cr3+ center (TE center I), Cr3+-VM (OR center III) and Cr3+-Li+ (OR center IV), and the relevant distortions have been verified in Cs2CdF4 and K2CdF4 crystals. Three different structural models have been examined for OR Cr3+ centers. The reasonableness of these structural models has been discussed.

• 出版日期2016-3-1