Direct hydroxylation of benzene to phenol on Cu-V bimetal modified HMS catalysts

作者：Hu Liya; Yue Bin^*; Chen Xueying; He Heyong

来源：Catalysis Communications, 2014, 43: 179-183.

DOI：10.1016/j.catcom.2013.10.005

• Benzene
• Copper
• HMS
• Phenol
• Vanadium

A series of mesoporous Cu-x-V-HMS catalysts with different copper content were prepared by the co-synthesis method. The addition of copper improves the benzene adsorption ability of the catalyst and the redox property of vanadium species, which facilitate the benzene hydroxylation reaction. Among the catalysts studied, Cu-0.90-V-HMS exhibited the best catalytic activity with a phenol yield of 29.0% compared with 20.7% over V-HMS catalyst.

• 出版日期2014-1-5
• 单位复旦大学