Novel Preparation and Physicochemical Characterization of a Nanocrystalline Cobalt Ferrite System

作者：Deraz N M^*; El Aiashy M K; Ali Suzan A

来源：Adsorption Science and Technology, 2009, 27(8): 797-810.

DOI：10.1260/0263-6174.27.8.797

Well-defined CoFe(2)O(4) nanoparticles with an average grain size of about 50 nm were successfully synthesized by a combustion method employing different ratios of fuel to cations within the range 0-2.67. The as-prepared powders were characterized and investigated by TG, XRD, IR, SEM, TEM and VSM methods, and via isopropanol conversion at 250-450 degrees C.
The results showed that increasing the ratio between fuel and cations stimulated the formation of cobalt ferrite due to the increasing flame temperature. Changing the fuel/cation ratio brought about modificadons in the structure, surface activity, selectivity and magnetic properties of the investigated solids. A fuel/cation ratio of 2 led to the formation of catalyst having a high activity (49%) and magnetization (77.54 emu/g). All the solids investigated behaved as dehydrogenation catalysts leading to the formation of acetone as the major product. The fuel/cation ratio did not alter the mechanism of dehydrogenation of isopropanol, but increased the concentration of active sites involved in the catalyzed reaction.

• 出版日期2009