Non-destructive radioanalytical technique in characterization of anion exchangers Amberlite IRN78 and Indion H-IP

作者：Singare P U^*

来源：Journal of Radioanalytical and Nuclear Chemistry, 2014, 299(1): 591-598.

DOI：10.1007/s10967-013-2793-3

• Non-destructive technique
• Radio analytical technique
• Reaction kinetics
• Ion-isotopic exchange reaction
• Amberlite IRN78
• Indion H-IP

The present study deals with characterization of industrial grade anion exchange resins Amberlite IRN78 and Indion H-IP for which non-destructive radiotracer technique using I-131 and Br-82 was used. The radioisotopes were used to trace the kinetics of iodide and bromide ion-isotopic exchange reactions taking place in the two resins. It was observed that under identical experimental conditions of 40.0 A degrees C, 1.000 g of ion exchange resins and 0.003 M labeled iodide ion solution for iodide ion-isotopic exchange reaction, the values of specific reaction rate (min(-1)), amount of iodide ion exchanged (mmol), initial rate of iodide ion exchange (mmol min(-1)) and log K (d) were 0.285, 0.544, 0.155 and 12.6 respectively for Amberlite IRN78 resin, which was higher than 0.093, 0.315, 0.029 and 4.9 respectively as that obtained by using Indion H-IP resins. Also at a constant temperature of 40.0 A degrees C, as the concentration of labeled iodide ion solution increases 0.001-0.004 M, the percentage of iodide ions exchanged increases from 68.10 to 74.00 % for Amberlite IRN78 resin, which was higher than the increase of 40.20-42.80 % as observed for Indion H-IP resins. The identical trend was observed for the two resins during bromide ion-isotopic exchange reaction. The overall results indicate that that under identical experimental conditions Amberlite IRN78 resins shows superior performance over Indion H-IP resins.

• 出版日期2014-1