Macrocyclic Hamilton-type receptors comprising a ferrocene pivot

作者:Pisciottani Luca; Douarre Maxime; Bibal Brigitte; Davies Clotilde; Roberts Holly; Kauffmann Brice; Horswell Sarah L; Tucker James H R*; McClenaghan Nathan D*
来源:Supramolecular Chemistry, 2018, 30(10): 869-875.
DOI:10.1080/10610278.2018.1426856

摘要

Synthetic hydrogen-bonding receptors are described, which incorporate a central electroactive ferrocene moiety grafted with two adjacent bis(amido)pyridine motifs and an aliphatic tether (14 and 18 methylene units for 1 and 2, respectively) completing the macrocycle. The crystallographic structure, barbiturate guest-binding studies and electrochemical data are provided for the more strongly-binding macrocycle 2.
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  • 出版日期2018