Novel stereocontrolled amidoglycosylation of alcohols with acetylated glycals and sulfamate ester

作者:Murakami Teiichi*; Sato Yukari; Yoshioka Kyoko; Tanaka Mutsuo
来源:RSC Advances, 2014, 4(41): 21584-21587.
DOI:10.1039/c4ra02367f

摘要

A regio- and stereo-controlled, one-pot amidoglycosylation of alcohols has been achieved using O-acetylated glycals, trichloroethoxysulfonamide, and iodosobenzene in the presence of a rhodium(II) catalyst. The reaction would proceed via stereoselective intermolecular aziridination of the glycal.

  • 出版日期2014