A NEW EXO-TRIDENTATE TRIS-PYRIDINE LIGAND DERIVED FROM 3-OXA-1,5-DIAZABICYCLO[3.3.1]NONANE AND ITS DINUCLEAR CU(II) COMPLEX. SYNTHESIS AND CRYSTAL STRUCTURES

作者：Madalan Augustin M^*

来源：Romanian Journal of Chemistry, 2013, 58(9-10): 829-+.

• tridentate ligands
• copper(II) complexes
• polynuclear complexes
• molecular structure.

A new exo-tridentate tris-pyridine ligand (L), derived from 3-oxa-1,5-diazabicyclo[3.3.1]nonane, has been synthesized and structurally characterized by X-ray diffraction on single crystal. A dinuclear complex, [{Cu(acac)(phen)}(2) (L)](ClO4)(2)center dot 5H(2)O, was obtained using this bridging ligand and also structurally characterized by X-ray diffraction on single crystal.

• 出版日期2013-10