Microporous structures having phenylene fin: Significance of substituent groups for rotational linkers in coordination polymers

作者：Matsuda Ryotaro^*; Kosaka Wataru; Kitaura Ryo; Kubota Yoshiki; Takata Masaki; Kitagawa Susumu

来源：Microporous and Mesoporous Materials, 2014, 189: 83-90.

DOI：10.1016/j.micromeso.2013.10.029

• Porous coordination polymers
• Metal-organic frameworks
• Adsorption
• Micropore

Microporous coordination polymers having various shaped apertures were synthesized and crystallographically characterized using substituted terephthalate ligands. The substituents exert a notable influence on the channel size and shape depending on the orientations and disordering of the phenylene units such as a fin. This is a new aspect of porous coordination polymers, which would provide important information for a precise design of the micropore.

• 出版日期2014-5-1
• 单位RIKEN